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January 2011 issue
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Cover illustration: The structure of the organic cation and oligomer of 2,4-dimethylpyridinium hexa--bromido-tetrabromidotetracuprate(II), showing the atom-labeling scheme. Displacement ellipsoids are drawn at the 50% probability level. See Kelley, Akkina, Devarapally, Nalla, Pasam, Madhabushi & Bond [Acta Cryst. (2011), C67, m22-m34].
editorial
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international union of crystallography
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inorganic compounds
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The previously unknown crystal structure of Sr2.36Mg2.64P4O15, which was thought to be stoichiometric Sr2Mg3P4O15, has been determined and refined from laboratory powder X-ray diffraction data, representing a new structure type.
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This represents the first detailed structural analysis of an anhydrous phosphate containing both zirconium and aluminium. The structure features a complicated three-dimensional framework of [AlZr2(PO4)4] constructed by PO4, AlO4 and ZrO6 polyhedra interconnected via corner-sharing O atoms, and one-dimensional Cs chains which are located in the infinite tunnels within the [AlZr2(PO4)4] framework, which run along the c axis.
metal-organic compounds
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organic compounds
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